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Due to environment and sustainability regulation in the last decades considerable performance in green technology in the field of materials science through the development of biocomposites could be noticed. Thus, the development of high-performance materials produced from natural resources expands worldwide. This can be attributed mainly due to their assets compared to their synthetic contourparts like low cost, low weight, less damage to processing equipment, improved surface finish of moulded parts composite, good mechanical properties, biodegradability, abundant and renewable resources. Natural fibres are valuable and versatile resources with multiple advantages. Nowadays all the more, the automotive industry is under increasing pressure to fulfill environmental and performance demands and higher fuel efficiency at competitive costs. Automakers recognize potential in biocomposites if these materials can offer the same performance as traditional composites but with lower weight. Additional they exhibit non-brittle fracture on impact, which is another significant requirement for automotive sector. Other drivers that scores for use of natural fibres reinforced polymer composites (NFRPC) in automotive applications imply reduced waste disposal, reduction of greenhouse gas emission and Life Cycle Consideration. In spite of their benefits, the significant challenge for producers and supplier to handle with natural fiber reinforced polymer composites resides in large inconsistency of their properties. The chemical composition of vegetal fibres relies on several factors comprising fiber variety, time of harvesting, climatic history, soil characteristics and fibre processing technology. All these factors exert an influence on their final properties when used as reinforcements in biocomposite materials. In this review a wide range of issues is addressed with special reference to mechanical properties of fibres, interface adhesion and environmental implication of NFRPC. The discussion on the cellulosic/lignocellulosic fibre properties is conducted in order to relate their chemical composition, microstructure and mechanical properties and to understand their use and limits as reinforcements in composite materials. The variation within the mechanical properties of natural fibres is a challenge towards designing predictable components for industry since the engineers are accustomed to the precise and reproducible properties of synthetic fibres. The hydrophilic nature of lignocellulosic fibres causes poor resistance to moisture and incompatibility to hydrophobic polymer matrix. As a consequence, this incompatibility causes a weak fibre/matrix interface, which consecutively leads to diminished mechanical properties of the biocomposites. Therefore, it is important to ensure a good adhesion between matrix and fibres to enhance the mechanical strength of NFRPC. This study aims to provide an overview of the greener surface treatments without use of hazardous chemicals, with emphasize on the enzymatic surface modification of natural fibres. The effectiveness of the treatment on the mechanical properties of the resulting NFRPC is also reviewed. Environmental impact of NFRPC is another important issue addressed in this review. A comparison of the environmental impacts between the NFRPC and SFRPC applied in the automobile sector, based on LCA studies, will be traced.

natural fibres; biocomposite; interfacial adhesion; mechanical properties; environmental impact